Based on the experimental data of Kp measured In this paper, the thermodynamic calculation of Kp from Kr and equation of state was studied and it was found that the chemical equilibrium of methanol synthesis can be described well by using Cheredeichenko (1968)'s Kr, 00 and Blssett (1977)' s Kr. rs relationship and a modified SRK equation. Meanwhile, the equilibrium constant Kr In methanol synthesis In literature since 1930s were appraised. It was found that the obvious deviations of Kr values of different authors would be given because of different basic thermochemical data and the accumulations of the deviations.
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Liu et al. (1994) studied this question.
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