January 10, 2013Angewandte Chemie International Edition

Enantio‐ and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

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YNYota NishiokaKyushu University TUTatsuya UchidaKyushu University TKTsutomu KatsukiKyushu University

Abstract

Smooth salen: Ru(CO)–salen complex 1 is an effective catalyst for asymmetric benzylic and allylic CH bond amination using 2-(trimethylsilyl)ethanesulfonyl azide (SESN3) as the nitrene source. The reaction proceeded with high enantioselectivity and excellent regioselectivity. An ethyl group can be selectively aminated, even in the presence of an n-propyl group. No migration or isomerization of the double bond was observed.

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Nishioka et al. (2013) studied this question.

synapsesocial.com/papers/6a9d5679f025b578bcd9ace8 https://doi.org/10.1002/anie.201208906

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Enantio‐ and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

Abstract

Discussion

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Cite This Study

Enantio‐ and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

Abstract

Discussion

Member takes

Cite This Study

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