Détermination directe des coefficients du potentiel de Dunham par une méthode de moindres carrés non linéaire appliquée aux nombres d'ondes des raies. Application au cas de la molécule HBr

In this paper, the Dunham potential coefficients are numerically determined by using a nonlinear least squares routine applied directly to the line experimental wave numbers.The results are compared to the ones obtained when using the usual iterative process applied to the H81Br Yi0 and Yi1 equilibrium constants.The al determination new method assumes a theoretical framework (B.O., adiabatic or non-adiabatic) to be valid. One can test this assumption by comparing the experimental data to the calculated ones.