Living ring-opening polymerization of 2-alkoxy-1-methylenecyclopropanes has been achieved by π-allyl Pd complexes to afford polymers having alkoxy and vinylidene groups in the repeating units. A cyclic dinuclear Pd complex has been synthesized and utilized for the synthesis of cyclic polymers and block copolymers with narrow molecular weight distribution.
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Takeuchi et al. (2006) studied this question.
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