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October 15, 2009Chemistry - A European Journal

Synthesis of a Thorium Tuck‐In Complex, [(η5:η1‐C5Me4CH2)(η5‐C5Me5)Th{iPrNC(Me)NiPr}], by CH Bond Activation Initiated by (C5Me5)−

William J. Evans Justin R. Walensky Joseph W. Ziller

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Abstract

Tuck in! (C5Me5)− effects alkyl CH bond activation (Th) and reduction (U) with the cationic complexes [(C5Me5)2An{iPrNC(Me)NiPr}][BPh3Me] to form the first structurally characterized thorium complex that contains a tuck-in metalated (C5Me5CH2)2− ligand (see figure) and a trivalent metallocene amidinate [(C5Me5)2U{iPrNC(Me)NiPr}].

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Evans et al. (2009) studied this question.

synapsesocial.com/papers/6a9d7a6ba99ff5a58a67fcd6 https://doi.org/10.1002/chem.200901942

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Synthetic Utility of [(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Ln][(μ-Ph)<sub>2</sub>BPh<sub>2</sub>] in Accessing [(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>LnR]<i><sub>x</sub></i> Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation ReactivityOriginal Research · 2005 · 109 citations
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5An Unprecedented Type of Linear Metallocene with an f-ElementOriginal Research · 2006 · 62 citations

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