The heteroaromatic anion lithium 2-(diisopropylamino)-1,2-thiaborolide ( 3 ) has been prepared by a synthesis using the Grubbs ring-closing metathesis. 3 has been converted to the Cp*Ru complex 10, the Cp*ZrCl 2 complex 11, and the Me 2 Si-bridged CpZrCl 2 complex 15 .
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Ashe et al. (2000) studied this question.
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