The 2,4,6-trithiocyanurate complex [2,4,6-C3N3(SAuL)3] is stable when L = triphenylphosphine, but when L = tert-butyl isocyanide, it reacts to give the hexagold(I) complex [{C3N3(AuL)(SAuL)S2(μ-Au)}2], which contains short intramolecular Au···Au bonds and forms a novel two-dimensional sheet structure through intermolecular Au···Au bonding.
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Hunks et al. (1999) studied this question.
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