Effect of Pore Distribution on Microstructure Development: III, Model Experiments

Model experiments have been conducted on a series of alumina samples in which the microstructures have been tailored to conform to the classical configuratins depicted in the models of final‐stage sintering. Simultaneous measurements of sintered density, grain size, pore number density, and pore size distribution were made as a function of sintering time at constant temperature (1850°C). The data supported a model of grain‐boundary‐diffusion‐controlled densification and surface‐diffusion‐controlled grain growth. An atom flux equation for grain‐boundary diffusion transport was deduced from the data. The kinetics analysis highlights the importance of incorporating the number of pores per grain as an independent variable in mechanistic studies of final‐stage sintering. The number of pores per unit volume was identified as a critical factor influencing densification kinetics. The effect of pore distribution on microstructure development was simulated for comparison with the data obtained from the model experiments.