Key result
Perovskite membrane-assisted fluidized bed reactors outperformed ordinary reactors for autothermal reforming of methane, achieving high CH4 conversion and H2 yield.
Perovskite membrane-assisted fluidized bed reactors outperform ordinary reactors for autothermal reforming of methane.
Hypothesis-generating for perovskite membrane reactors in hydrogen production; leaves open scalability and durability validation.
The performance of perovskite membrane-assisted fluidized bed reactors for ultra-high purity hydrogen production through autothermal reforming of methane has been investigated using numerical simulations. Two different three-phase phenomenological models have been developed differing in their description of the mass transfer between the membranes and the emulsion, cloud and bubble phases, where the parameters in the oxygen permeation flux expression were determined from new experimental data. The calculation of the required oxygen-to-carbon ratio is based on overall enthalpy balance. The reactor performance without and with O2 permeable perovskite membranes have been investigated and compared. The two models of perovskite membrane-assisted fluidized bed reactors produce basically the same results, indicating that the external mass transfer from the membranes to the bulk of the fluidized bed is not rate limiting, but clearly show that the fluidized bed membrane reactor can largely outperform ordinary fluidized bed reactors for the autothermal reforming of methane. It has been demonstrated that with perovskite membrane-assisted fluidized bed reactors autothermal operation with a high CH4 conversion and H2 yield can be achieved with a relatively small catalyst inventory.
No takes yet. Share an insight, caveat, or question.
Y F Dajani (1977) studied this question. Perovskite membrane-assisted fluidized bed reactors vs. Ordinary fluidized bed reactors was evaluated on CH4 conversion and H2 yield. Perovskite membrane-assisted fluidized bed reactors outperformed ordinary reactors for autothermal reforming of methane, achieving high CH4 conversion and H2 yield.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: