Possessing an extra anionic handle for chiral supramolecular interactions, 2,6-anthracenedicarboxylate exhibited greater photochirogenic performance than 2-anthracenecarboxylate to afford the anti -cyclodimer in up to 94% yield and −72% enantiomeric excess upon photoirradiation with dicationic γ-cyclodextrins.
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Wang et al. (2020) studied this question.
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