The red limit potential of electron photoemission was measured in various polar solvents, and the apparent solvation free energies of the electrons were estimated. The energy state and transformation of photoemitted electrons in solution were discussed as regards the role of dry or damp electrons as an intermediate species. A proportionality between the intermediate solvation free energy and the energy quantum of the optical absorption band maximum of solvated electron in various polar solvents is pointed out.
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Yamashita et al. (1977) studied this question.
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