Optically active polymers containing P-stereogenic bisphosphine and 1,2,3-triazole units in the main chain were obtained by copper-catalyzed Huisgen cycloaddition. The repeating unit of the polymer adopted bidentate as well as tetradentate coordination, leading to the change in the conformations of the polymer via complexation with transition metals.
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Imoto et al. (2010) studied this question.
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