A partially cleaved 1,3,5-triphosphaprismane derivative 1 is formed in the coordination sphere of vanadium when tBuCP is allowed to react with η6-naphthalene (η5pentamethylcyclopentadienyl) vanadium in THF. The triphosphaprismane derivatives exhibits dynamic behaviour in solution at room temperature, and it undergoes a facile reaction with CO to give the dark-green 1,3,5-triphospha-Dewar benzene complex 2.
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Milczarek et al. (1987) studied this question.
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