A soap/alcohol miniemulsion in combination with an homogenized mixture of monomer and initiator is utilized to generate PVC plastisol. Droplet distributions generated consist of two distinct types. Judicious control of soap‐to‐alcohol ratio allows control of the number and size of the smaller droplet family; homogenization and initiator water solubility affect the other. Final latex particle distribution may be unimodal or bimodal depending upon manipulation of these factors.
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Dewald et al. (1984) studied this question.
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