A local effective potential, H ex has been used to account for electron exchange, together with a model hamiltonian for the helium atom in Kohn's variational approximation to the electron helium scattering length, a. H ex was chosen to give agreement with the Born-exchange and static-exchange approximations. Correlation was introduced in the 84 term that trial function by using interelectronic coordinates. The method provides an upper bound to the 'model' scattering length and the value of 1.16a 0 was obtained in good agreement with more elaborate calculations and with experiment.
No takes yet. Share an insight, caveat, or question.
S. K. Houston (1973) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: