Platinum has been inserted into corroles for the first time and three oxidized Pt(IV)(corrole˙(2-))ArAr' complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl → corrole˙(2-) charge transfer character in these transitions.
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Alemayehu et al. (2014) studied this question.
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