Several chiral polar mesogens are described. The existence of the reentrant cholesteric phase is discussed from a molecular structure point of view (chain length, central cores). Compound 1c (n = 3) provides the first example of a double reentrant sequence: K-SA-N*rc-SA-N*-I. In addition, we have obtained the chiral variant of some new smectic modifications: Sc2*, Sc*…
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Destrade et al. (1985) studied this question.
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