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Abstract The cleavage/functionalization of C–C bonds in alcohols has emerged as a robust tool for exploration of new conversion. Herein, a Mn(OAc)2-catalyzed oxidative cleavage/ammoxidation of a wide range of alcohols to amides has been developed. The practicality of this transformation was demonstrated by a scale-up experiment and an amidation of mixed alcohols in a one-pot fashion. Moreover, a plausible mechanism was proposed based on a series of control experiments.
Li et al. (2023) studied this question.