A 1:2 mixture of (P1)(AuCl)2 [P1=(S)‐DTBM‐MeO‐BIPHEP] and silver tetrafluoroborate (AgBF4) in methanol catalyzes the intramolecular hydroamination of unactivated alkenes with carbamates and ureas to form pyrrolidine derivatives with up to 85% ee. magnified image
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Lee et al. (2014) studied this question.
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