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July 1, 2002Chemistry Letters

A Chemical Modification of a Mn12 Single-Molecule Magnet by Replacing Carboxylate Anions with Diphenylphosphate Anions

Takayoshi Kuroda‐Sowa Satoshi Fukuda Shinsuke Miyoshi Masahiko Maekawa Megumu Munakata Hitoshi Miyasaka Masahiro Yamashita

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Abstract

Diphenylphosphate anions can replace with benzoate anions of [Mn12O12(O2CPh)16(H2O)4] to afford a novel Mn12 single-molecule magnet (SMM) with mixed bridging ligands.

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Kuroda‐Sowa et al. (2002) studied this question.

synapsesocial.com/papers/6a9e3f4d74bfeee0946aac72 https://doi.org/10.1246/cl.2002.682

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1High-spin molecules: [Mn12O12(O2CR)16(H2O)4]Original Research · 1993 · 2,287 citations
2Single-Molecule Magnets: Jahn−Teller Isomerism and the Origin of Two Magnetization Relaxation Processes in Mn<sub>12</sub> ComplexesOriginal Research · 2001 · 159 citations
3Effects of Paramagnetic Ferrocenium Cations on the Magnetic Properties of the Anionic Single-Molecule Magnet [Mn12O12(O2CC6F5)16(H2O)4]-Original Research · 2001 · 72 citations
4Single-Molecule Magnets: Site-Specific Ligand Abstraction from [Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CR)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>] and the Preparation and Properties of [Mn<sub>12</sub>O<sub>12</sub>(NO<sub>3</sub>)<sub>4</sub>(O<sub>2</sub>CCH<sub>2</sub>Bu<i><sup>t</sup></i>)<sub>12</sub>(H<sub>2</sub>O)<sub>4</sub>]Original Research · 2001 · 138 citations
5Single-Molecule Magnets: Ligand-Induced Core Distortion and Multiple Jahn−Teller Isomerism in [Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CMe)<sub>8</sub>(O<sub>2</sub>PPh<sub>2</sub>)<sub>8</sub>(H<sub>2</sub>O)<sub>4</sub>]Original Research · 2001 · 133 citations

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