A direct experimental determination of the equilibrium constant for the isotope exchange reaction Li7(s) + 6LiBr(soln) = 6Li(s) + 7LiBr(soln) has been made using an electrochemical cell without liquid junction. The value obtained is K = 1.037 ± 0.004 at 23°C in diglyme as solvent. The value obtained has been compared with values calculated from statistical thermodynamic theory.
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Hall et al. (1969) studied this question.
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