The major metabolic pathway for profenofos in cotton involves cleavage of the phosphorothioate ester to yield 4-bromo-2-chlorophenol followed by conjugation with sugars. This investigation found a unique sugar conjugate in cotton stalks and seed. The unique metabolite is identified as a glucosylsulfate conjugate of 4-bromo-2-chlorophenol, and its isolation and structure elucidation are reported.
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Capps et al. (1996) studied this question.
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