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Knowledge of local monomer concentrations in the case of heterogeneous polymerizations is extremely important, since these local concentrations determine the kinetics of the reactions. In this paper two techniques to determine the local concentrations are reported. The first technique makes use of the well known pulsed initiation method, which is frequently used nowadays for the experimental determination of the propagation rate constant (kρ). The second technique is applied for the determination of monomer concentrations in vesicle bilayer structures.
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German et al. (1996) studied this question.
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