January 1, 1986Journal of the Chemical Society Chemical Communications

Palladium-catalysed preparation of 1,2-dienes by selective hydrogenolysis of alk-2-ynyl carbonates with ammonium formate

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Abstract

1,2-Dienes were prepared by the selective hydrogenolysis of alk-2-ynyl carbonates with HCO2NH4 catalysed by Pd2(dba)3·CHCl3–PBun3(dba = dibenzylideneacetone).

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Cite This Study

Tsuji et al. (1986) studied this question.

synapsesocial.com/papers/6a9e68557f3dc8df7ef58451 https://doi.org/10.1039/c39860000922

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Abstract

1,2-Dienes were prepared by the selective hydrogenolysis of alk-2-ynyl carbonates with HCO2NH4 catalysed by Pd2(dba)3·CHCl3–PBun3(dba = dibenzylideneacetone).