Reactivity of copper(I) complexes [Cu(L)]+ containing a series of tetradentate tripodal ligands, (6-methyl-2-pyridylmethyl)m(2-pyridylmethyl)(3−m)amine (m = 1, 2, or 3) with molecular oxygen was investigated in acetone at −70 °C. It was found that the introduction of 6-methyl group(s) into pyridyl group(s) has significant influences on the stereochemistry and thermal stability of peroxo dicopper(II) complexes.
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Uozumi et al. (1993) studied this question.
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