February 1, 1977Bulletin of the Chemical Society of Japan

Metal Phosphinylides and Phosphinothioylides. VII. The Structure of [Ph2PX]M (X=O, S) in Solution and Their Disproportionation

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Abstract

The species [Ph2PO]M in THF were found to exist as Ph2P–O–M by 31P-NMR, and [Ph2PS]MgCl as Ph2P–S–MgCl by Raman spectrum. The species [Ph2PS]M undergo easy disproportionation by heating.

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Goda et al. (1977) studied this question.

synapsesocial.com/papers/6a9e71484bbd51f2272cc2b5 https://doi.org/10.1246/bcsj.50.545

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Abstract

The species [Ph2PO]M in THF were found to exist as Ph2P–O–M by 31P-NMR, and [Ph2PS]MgCl as Ph2P–S–MgCl by Raman spectrum. The species [Ph2PS]M undergo easy disproportionation by heating.

Metal Phosphinylides and Phosphinothioylides. VII. The Structure of [Ph2PX]M (X=O, S) in Solution and Their Disproportionation

Abstract

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Cite This Study

Metal Phosphinylides and Phosphinothioylides. VII. The Structure of [Ph2PX]M (X=O, S) in Solution and Their Disproportionation

Abstract

Discussion

Cite This Study

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