The Intramolecular addition of a titanocene vinylidene complex formed by dechlorodimethylalumination of a 1-dimethylalumino-1-bis(η5-cyclopentadienyl)chlorotitano-alkene to an unactivated alkene or alkyne affords bicyclic titanacyclobutanes or titanacyclobutenes.
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Dennehy et al. (1990) studied this question.
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