Crystalline Cd(SPh)2 is {(μ‐SPh)6Cd4(μ‐SPh)4/2}, an inorganic polymer. It consists of Cd4(SPh)6 cages having adamantane‐like structure, each of which is linked with four surrounding cages by four SPh bridges. The three‐dimen‐113Cd‐NMR spectrum indicates that the polymer forms Cd10(SPh)20 molecules having tetraadamantanoid structure upon solution in dimethylformamide.
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Craig et al. (1986) studied this question.
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