Guests welcome: Complex formation between AgI ions and a Zn-porphyrin ligand (L) possessing four 2,2′-bipyridyl groups produced a dimeric complex [Ag4L2]4+, wherein the interplane distance between the Zn-porphyrin groups was ideal for intercalation of aromatic molecules through π–π interactions. The cofacial dimer [Ag4L2]4+ serves as an excellent receptor for π-electron-deficient guests.
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Nakamura et al. (2013) studied this question.
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