A copper–copper separation of about 2.84 Å is determined by extended X-ray absorption fine structure studies for the (μ-1,2-peroxo)dicopper(II) species 1, which has only a 1,8-naphthyridine unit as an additional bridge. Complex 1 was prepared by the reaction of O2 with a dicopper(I) complex formed from BPMAN (see picture).
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He et al. (2001) studied this question.
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