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It is demonstrated numerically that detailed balance indeed is well satisfied in the multi-state impact parameter formulation of proton-hydrogen atom collisions. It is also demonstrated numerically that detailed balance is a much more sensitive test of computational accuracy than is the charge conservation test usually employed in such impact parameter calculations. It is suggested that detailed balance be used as a check on all impact parameter calculations. That even agreement with detailed balance may not be a sufficient test for accuracy of the results is pointed out.
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Tai et al. (1973) studied this question.
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