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The Debye–Hückel theory of electrolyte solutions is extended to take account of the so-called fluctuation potential. An oscillation in the Debye–Hückel potential for symmetrical electrolytes is predicted at approximately κa = 1.495 and the corresponding oscillation in the mean potential of the double layer pointed out. A simple derivation of the oscillation predicted by Kirkwood and Poirier is also given.
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C.W. Outhwaite (1969) studied this question.
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