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The Mössbauer parameters ΔEQ (quadrupole splitting) and δ (the chemical shift) for iron compounds are discussed in relation to the electronic properties of the iron atoms, the known structural and magnetic properties of the compounds, their absorption spectra, and the ligand field strengths. The structural significance of the results obtained for some of the compounds experimentally studied in this work and elsewhere is given.
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Brady et al. (1965) studied this question.
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