The reaction of cis- Fe(dmpe) 2 H 2 ( 1 ) with 13 C-labeled carbon dioxide (CO 2 ) was investigated, and trans -[Fe(dmpe) 2 (CO)H]·[HCO 3 ] ( 5 ) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO 2, and this effectively constitutes a disproportionation of CO 2 to CO and CO 3 2− . trans -[Fe(dmpe) 2 (CO)H].[HCO 3 ] ( 5 ) was characterized by crystallography and by NMR spectroscopy.
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Allen et al. (2008) studied this question.
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