The first ruthenium(II) 1,2,3-trimethylindenyl complexes have been prepared, including allenylidene, alkynyl, and alkenylcarbene derivatives. The X-ray crystal structure of [Ru( C C CPh 2 )(η 5 -1,2,3-Me 3 C 9 H 4 )(CO)(PPh 3 )] [BF 4 ] is described.
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Gamasa et al. (1997) studied this question.
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