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Inorganic solid surfaces which have various surface free energies, 30∼65 dyn/cm, were probed using a Si 3 N 4 cantilever tip. It was found that the attractive force (∼10 -7 N), which is generated when a cantilever tip moves away from a solid surface after making contact, is more sensitive to the behavior of surface free energy than that (∼10 -9 N) which is generated when the tip moves toward the surface. The relationship between the elastic potential energy of the cantilever and the adhesion energy of the tip-surface system is also discussed.
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Kawai et al. (1992) studied this question.
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