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The peroxide curing of highly saturated nitrile rubber was analyzed. Reactions such as chain scission occurred that account for the drop in physical properties. The results are compared with an alternative cross‐linking that is currently being assessed. With a new curing agent the chain‐scission reaction was not present and the properties of the compounds were improved. Finally, an estimation of the free volume of the materials tested was attempted by using the WLF equation.
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Hernández et al. (1994) studied this question.
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