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The X band EPR spectrum of the (FeOF5)4− cluster in KZnF3 single crystals was analysed. We used a computer diagonalization for both the Zeeman interaction and the axial crystal field term and a perturbation treatment for the cubic field term and for the shf interaction. This cluster appears to be well adapted for EPR investigations of the structural properties of fluoperovskites.
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Buzaré et al. (1976) studied this question.
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