C45‐ and C50‐Carotenoids: Synthesis of Optically Active Cyclic C20‐Building Blocks and of (2R,2′R)‐2,2′‐Bis(4‐hydroxy‐3‐methyl‐2‐butenyl)‐β,β‐carotene ( = C.p. 450) The synthesis of the optically active C20‐building blocks (R)‐26 and (R)‐39 and of the optically active cyclic C50‐carotenoid C.p. 450 (3) starting from (−)‐β‐pinene is reported.
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Wolleb et al. (1986) studied this question.
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