How does it fit? The one-dimensional coordination polymer [Ag4L3{O2C(CF2)3CF3}4(EtOH)2]n (1; L=tetramethylpyrazine, see scheme) eliminates coordinated ethanol in an intramolecular substitution reaction. The reaction occurs in a single-crystal-to-single-crystal transformation and leads to extrusion of ethanol from the nonporous crystals. The reverse reaction involving uptake of ethanol vapor has been verified using X-ray powder diffraction.
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Libri et al. (2008) studied this question.
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