The transfer constants of 1‐dodecanethiol and non‐ionic thiol‐ended surfactants (transurfs) have been determined for the bulk polymerization of styrene at 70°C; these values are 19 for l‐dodecanethiol and 19 and 14 for the transurfs with 17 and 90 ethylene oxide units, respectively. Transfer constants are obtained from the high‐molecular‐weight portion of the full number molecular weight distribution.
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Vidal et al. (1996) studied this question.
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