A dodecanuclear chromium sulfide cluster complex [Cr12S16(PEt3)10] has been synthesized by the reaction of a hexanuclear cluster complex [Cr6S8(PEt3)6] with sulfur. This complex has two octahedral Cr6S8 cores that are linked by two Cr-S bonds. The intercluster bonding mode is similar to that in the Chevrel phases. Cyclic voltammetry shows the existence of the intercluster electronic interaction between the two Cr6S8 cluster units.
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Kamiguchi et al. (1996) studied this question.
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