The molybdenum-nickel cubane-type cluster [Mo3NiS4(H2O)10]4+ uptakes carbon monoxide in dilute HCl to give a new cluster [Mo3NiS4(CO)(H2O)9]4+. The X-ray structure analysis verified that the nickel atom has a tetrahedral configuration surrounded by one CO and three S’s neglecting three Ni-Mo bonds.
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Shibahara et al. (1993) studied this question.
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