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The effects of 2537 Å radiation upon solutions of hexacyanoferrate(II) were investigated at 25°C, using specific scavengers for hydrated electrons (N2O, H3O + , and NO3−) and for hydrogen atoms (CH3OH and C2H5OH). In the presence of N2O or NO3−, a photo-oxidation reaction giving hexacyanoferrate(III) was found to take place, the primary process being: [Fe(CN)6]4−ν[Fe(CN)6]3−+e−aq The quantum yield of this photochemical process was determined to be 0.35 at 25°C. The e−aq thus formed reacted with N2O, NO3−, and H3O+ , just like the hydrated electron produced in water irradiated with fast electrons or γ-rays.
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Shinichi Ohno (1967) studied this question.
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