You'll never walk alane: An intriguing T-shaped platinum–alane adduct results from the almost quantitive reaction of [Pt(PCy3)2] with AlX3 (X=Cl, Br, I). The compound [(Cy3P)2PtAlCl3] represents the first neutral alane complex displaying an unsupported Pt–Al dative bond.
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Braunschweig et al. (2007) studied this question.
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