Experimental study demonstrates a one-dimensional zinc coordination polymer that forms two-dimensional sheets via hydrogen bonding, highlighting its distinct structural and thermal properties.
A new coordination polymer, [Zn(BDOA)(Py) 2 (H 2 O)] n ( I ) (BDOA = benzene-1,4-dioxylacetate, Py = pyridine), has been prepared via self-assembly of benzene-1,4-dioxylacetate with zinc nitrate under mild conditions and characterized by IR spectra, elemental analysis and X-ray diffraction single-crystal analysis. The complex crystallizes in the monoclinic system, space group C 2/ c with a = 15.5751(9), b = 6.0898(4), c = 21.7133(13) Å, V = 1991.9(2) Å 3 , β = 104.719(1)°, Z = 4. The zinc atoms are bridged by BDOA ligand, forming a one-dimensional chain along the z axis. A two-dimensional layer structure is formed by the intermolecular hydrogen bonds. The thermal decomposition profile of the complex is reported as well.
No takes yet. Share an insight, caveat, or question.
Li et al. (2013) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: