Abstract 2-Alkoxybenzothiazolium salts, formed in situ from 2-fluorobenzothiazolium salt and alcohols, reacted with iodide, bromide, and chloride ion to give the corresponding alkyl halides in good yields. The present procedure afforded a convenient method for the preparation of highly optically active alkyl halides such as 2-halooctanes.
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Hojo et al. (1976) studied this question.
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