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Three novel coordination polymers, [LnCu(PZDC)3].[Ln(H2O)9]0.5.[(H2O)7H+]0.5 [Ln = La (1), Eu (2), Gd (3)], were synthesized. They are the first 3d-4f heterometallic framework with supramolecular 1D channels, in which lanthanide hydrate cations and lattice water molecules are located.
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Wang et al. (2007) studied this question.
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