The reactivity of “Li2[Pt(C≡CR)4]” and cis-[Pt(C≡CR)2COD] (R = tBu, Ph) towards PPh2H and PPh2(O)H has been investigated; it results in the synthesis of five types of alkynyl platinum compounds, for example, [{Pt(C≡CtBu) (PPh2O)3Li2(thf) (H2O)}2] (1). Displacement of PPh2(O)H by donor ligands in the compound [{Pt(C≡CR){(PPh2O)2H}(PPh2OH)] yields the related mononuclear complexes [Pt(C≡CR){(PPh2O)2H}L]n−
No takes yet. Share an insight, caveat, or question.
Falvello et al. (1999) studied this question.
Synapse has enriched one closely related paper. Consider it for comparative context: