Colossal Magnetoresistance in La0.7Ca0.3MnO3-δ: Comparative Study of Single-Crystal and Polycrystalline Material

The magnetoresistance (MR) and transport properties of both single-crystal and polycrystalline samples of La 0.7 Ca 0.3 MnO 3 - δ (LCMO) have been investigated to elucidate their magneto transport behaviors near and below the Curie temperature T C . We find that negative MR is heavily dependent upon the surface morphology in the low-temperature, ferromagnetic regime. The polycrystalline sample postannealed at 1400 °C under the oxygen atmosphere exhibits large low-field MR in the whole temperature range below T C, which is about 20% at 0.5 T. On the other hand, the single-crystal sample shows the remarkable suppression of resistivity only at the narrow temperature region near T C . We suggest that the MR found in the polycrystalline sample is dominated by the tunneling of spin-polarized electrons between grains below T C while the MR in the single crystal is mainly ascribed to the suppression of spin fluctuation. The difference in the MR property between the single-crystal and polycrystalline samples is discussed in terms of oxygen inhomogeneity and granular effects affected by interfacial melting.